| Competing Magnetic Interactions in a Dinuclear Ni(II) Complex: Antiferromagnetic O-H...O Moiety and Ferromagnetic $N_{3}^{-}$ Ligand (2006) | |||||||||
Abstract | |||||||||
| Synthesis, structural characteristics, magnetic studies and DFT calculations in Ni(II) dinuclear complexes containing two bridging $N_{3}^{-}$ and an O-H...O linkage reveal the existence of ferromagnetic interactions between Ni(II) centers via $N_{3}^{-}$ ligands and antiferromagntic interactions through the H-bonded moiety. The overall magnetic behavior of the system depends on the delicate balance between these two competing interactions. | |||||||||
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