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SYNTHESIS AND PROPERTIES OF SOME CYANURIC CHLORIDE DERIVATIVES (1998)

Abstract
Cyanuric chloride was reacted with several negatively substituted primary alcohols. Completely substituted reaction products were obtained with trifluoroethanol, tribromoethanol, pentaerythritol trinitrate, and pentaerythritol dinitrate. Di- and tri-substituted products were obtained with 2-methyl-2-nitro-1-propanol which has a tertiary nitro group, whereas alcohols with primary and secondary nitro groups did not react. The reaction with the potassium salt of nitroform gave a product which gradually decomposed on standing. The monoperchlorate salt of trihydrazino-s-triazine was obtained, but attempts at the preparation of perchlorate derivatives of aminoazido-s-triazines were unsuccessful. Sensitivity and stability data are reported on some of the products. (Author)

Publication details
Contributors BUREAU OF NAVAL WEAPONS WASHINGTON D C
Repository Defense Technical Information Center OAI-PMH Repository (United States)
Keywords *CYANOGEN CHLORIDES, *PROPELLANTS, *TRIAZINES, ALCOHOLS, CYANURIC ACIDS, ESTERS, HALOGEN COMPOUNDS, NITRO RADICALS, SYNTHESIS, *CYANOGEN CHLORIDES, CYANURIC ACIDS, NITRO RADICALS
Language eng