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Spreading of Trisiloxanes on Thin Water Film: Dry Spot Profile (2007)

Abstract
This paper reports the results of an experimental investigation of the spreading of trisiloxanes EO6, EO7, EO8, EO9 and sodium dodecyl sulphate SDS on thin films which are 320 microns in thickness; the concentrations covered are above the CMC. The spreading of SDS is accompanied by the formation of a “dry spot” which advances in time roughly as t1/4. The trisiloxanes spreading gave rise to dry spot formation that was accompanied by “irregularities”, which corresponded to an abrupt jump in the plot of dry spot radius versus time. The behaviour is attributed to a variety of factors: disjoining pressure effects or the fact that the Petri dish was too small so that backward propagating waves were set up due to reflections from the walls which interacted with the outspreading dry spot.

Publication details
Download http://ljs.academicdirect.org/A11/001_012.htm
http://www.doaj.org/doaj?func=openurl&genre=article&issn=15830233&date=2007&volume=6&issue=11&spage=1
Publisher AcademicDirect
Repository DOAJ-Articles (Sweden)
Keywords Marangoni Effect, Thin Film, Spreading, Trisiloxanes, Sodium Dodecyl Sulphate, Dewetting, Dry spot