Publication View

Spectral Editing in Solid-State MAS NMR Quadrupolar Nuclei using Selective Satellite Inversion (2007)

Abstract
A sensitivity enhancement method based on selective adiabatic inversion of a satellite transition has been employed in a (π/2)CT–(π)ST1–(π/2)CT spectral editing sequence to both enhance and resolve multisite NMR spectra of quadrupolar nuclei. In addition to a total enhancement of 2.5 times for spin 3/2 nuclei, enhancements up to 2.0 times is reported for the edited sites in a mixture of rubidium salts.

Publication details
Download http://hal.archives-ouvertes.fr/hal-00122562/en/
Publisher HAL - CCSD
Repository INRIA a CCSD electronic archive server based on P.A.O.L (France)
Keywords Chemical Sciences/Material chemistry, Quadrupolar Nuclei, Sensitivity enhancement, Inversion, Spectral editing
Type peer-reviewed article
Language English
Relation http://hal.inria.fr/docs/00/12/25/62/PDF/JMR-06-254-Rev.Submitted.pdf