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New mesophases formed by water soluble discoidal amphiphiles (1985)

Abstract
We present the first examples of lyotropic discotic nematic and columnar (hexagonal) mesophases obtained by dissolution of non-ionic, disk-like amphiphilic mesogens (hexa-polyethyleneoxy derivatives of triphenylene) in water. The phenomenon of « solvent driven aggregation » is shown to be a practicable route to new and novel mesophases with structures and properties intermediate to and encompassing those of the thermotropic and lyotropic-amphiphilic classes of liquid crystals.

Publication details
Download http://hal.archives-ouvertes.fr/jpa-00232518/en/
Publisher HAL - CCSD
Repository INRIA a CCSD electronic archive server based on P.A.O.L (France)
Keywords Physics/Physics archives, association, discotic liquid crystals, liquid crystals, nematic liquid crystals, organic compounds, lyotropic mesophases, discotic mesophases, nematic mesophases, columnar mesophases, water soluble discoidal amphiphiles, solvent driven aggregation
Type peer-reviewed article
Language English
Relation http://hal.archives-ouvertes.fr/docs/00/23/25/18/PDF/ajp-jphyslet_1985_46_7_325_0.pdf