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catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxylato] (2008)

Abstract
In the title compound, [Co(C14H8O4)(C18H10N4)]n, the CoII atom is six-coordinated by four O atoms from two different biphenyl-2,2′-dicarboxylate ligands and two N atoms from the bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand in a distorted octahedral geometry. The CoII atoms are bridged by the biphenyl-2,2′-dicarboxylate ligands to form a one-dimensional chain structure. π–π interactions between neighbouring chains result in a two-dimensional supramolecular network (centroid-to-centroid separation = 3.381 Å).

Publication details
Download http://scripts.iucr.org/cgi-bin/paper?S1600536808001827
http://www.doaj.org/doaj?func=openurl&genre=article&issn=16005368&date=2008&volume=64&issue=2&spage=m379
Publisher International Union of Crystallography
Repository DOAJ-Articles (Sweden)
Language eng