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1,1'-Binaphthalene-2,2'-diyl hydrogen phosphate (2008)

Abstract
The title compound, racemic bnppa, $C_{20}H_{13}O_4P$, crystallizes with four molecules in the asymmetric unit. Two independent centrosymmetric $O-H...O$ hydrogen-bonded tetramers, each involving two of the symmetry-independent molecules in the asymmetric unit generate the packing motif in the crystal structure. The hydrophobic parts of the tetramers connect to their neighbours via $C—H...\pi$ and \pi - \pi interactions [3.899 (2), 3.895 (2) and 3.803 (2) \AA within the symmetric unit, 3.851 (2), 4.000 (2), 3.988 (2) and 3.905 (2) \AA across centres of symmetry].

Publication details
Download http://eprints.iisc.ernet.in/archive/00014295/
http://eprints.iisc.ernet.in/archive/00014295/01/ln2013.pdf
Repository ePrints@iisc (India)
Keywords Solid State & Structural Chemistry Unit, Organic Chemistry
Type Journal Article