| Aquaazido{2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III) hemihydrate (2009) | |||||||||
Abstract | |||||||||
| In the title compound, [Mn(C20H14N2O2)(N3)(H2O)]·0.5H2O, the MnIII ion is chelated by the N,N′,O,O′-tetradentate Schiff base ligand and further coordinated by one azide ion and one water molecule in trans positions, resulting in a distorted fac-MnN3O3 octahedral arrangement. The O atom of the uncoordinated water molecule lies on a crystallographic twofold axis. In the crystal, O—H...O and O—H...N hydrogen bonds help to establish the packing. | |||||||||
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