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Spin-Resolved Photoemission on Anti-Ferromagnets: Direct Observation of Zhang-Rice Singlets in CuO (1997)

Abstract
We demonstrate that it is possible to obtain spin-resolved valence band spectra with a very high degree of spin polarization from antiferromagnetic transition metal materials if the excitation light is circularly polarized and has an energy close to the cation 2p3/2 (L3) white line. We are able to unravel the different spin states in the single-particle excitation spectrum of CuO and show that the top of the valence band is of pure singlet character, which provides strong support for the existence and stability of Zhang-Rice singlets in high-Tc superconductors.

Publication details
Download http://igitur-archive.library.uu.nl/phys/2001-0724-163927/UUindex.html
Publisher The American Physical Society
Repository DSpace at Utrecht University (Netherlands)
Keywords Natuur- en Sterrenkunde
Type Article / Letter to editor
Language English

Cited publications (1)
Polarized electrons at surfaces / J. Kirschner (1985)