A. P. Philipse

Publication List Details

Period

1993 - 2008

Number

62

Co-Authors

Model independent determination of colloidal silica size distributions via analytical ultracentrifugation (2008)

Planken, K.L., Kuipers, B.W.M., Philipse, A.P.

We report a method to determine the particle size distribution of small colloidal silica spheres via analytical ultracentrifugation and show that the average particle size, variance, standard...

Magnetic silica colloids for catalysis (2007)

Claesson, E.M., Mehendale, N.C., Koten, G. Van, Philipse, A.P.

Monodisperse magnetizable colloidal silica particles in a stable dispersion have been functionalized with a homogeneous catalyst: a PCP–pincer Pd-complex. In a proof-of-principle experiment we...

Measurement of the zero-field magnetic dipole moment of magnetizable colloidal silica spheres (2007)

Claesson, E.M., Erné, B.H., Bakelaar, I.A., Kuipers, B.W.M., Philipse, A.P.

The magnetic properties of dispersions of magnetic silica microspheres have been investigated by measuring the magnetization curves and the complex magnetic susceptibility as a function of frequency...

Thiol-functionalized silica colloids, grains, and membranes for irreversible adsorption of metal(oxide) nanoparticles (2007)

Claesson, E.M., Philipse, A.P.

Thiol-functionalization is described for silica surfaces from diverging origin, including commercial silica nanoparticles and Stöber silica as well as silica structures provided by porous glasses...

Thermodynamically Stable Pickering Emulsions (2007)

Sacanna, S., Kegel, W.K., Philipse, A.P.

We show that under appropriate conditions, mixtures of oil, water, and nanoparticles form thermodynamically stable oil-in-water emulsions with monodisperse droplet diameters in the range of 30–150...

Dipolar structures in magnetite ferrofluids studied with small-angle neutron scattering with and without applied magnetic field (2007)

Klokkenburg, Mark, Erné, B.H., Wiedenmann, A., Petukhov, A.V., Philipse, A.P.

Field-induced structure formation in a ferrofluid with well-defined magnetite nanoparticles with a permanent magnetic dipole moment was studied with small-angle neutron scattering (SANS) as a...

Rotational dynamics of magnetic silica spheres studied by measuring the complex magnetic susceptibility (2007)

Claesson, E.M., Erné, B.H., Philipse, A.P.

The weak permanent magnetic dipole moment of cobalt ferrite-doped colloidal silica spheres was increased by exposure to a saturating magnetic field. The resulting change of the rotational dynamics of...

Observation of a shape-dependent density maximum in random packings and glasses of colloidal silica ellipsoids (2007)

Sacanna, S., Rossi, L., Wouterse, A., Philipse, A.P.

We have measured the random packing density of monodisperse colloidal silica ellipsoids with a well-defined shape, gradually deviating from a sphere shape up to prolates with aspect ratios of about...

Effect of particle shape on the density and microstructure of random packings (2007)

Wouterse, A., Williams, S.R., Philipse, A.P.

We study the random packing of non-spherical particles by computer simulation to investigate the effect of particle shape and aspect ratio on packing density and microstructure. Packings of cut...

Spontaneous oil-in-water emulsification induced by charge-stabilized dispersions of various inorganic colloids (2007)

Sacanna, S., Kegel, W.K., Philipse, A.P.

Charge-stabilized dispersions of inorganic colloids are shown to induce spontaneous emulsification of hydrophobic (TPM) molecules to stable oil-in-water emulsions, with monodisperse, mesoscopic oil...

Preparation and properties of starch-based colloidal microgels (2002)

Dziechciarek, Y., Philipse, A.P.

Novel starch microgels were prepared by emulsion cross-linking and characterized with respect to shape, volume, and mass density. Starch microgels appear to be negatively charged (similar to-50 mV),...

Fluorous derivatives of [Rh(COD)(dppe)]BX4 (X=F, Ph): synthesis, physical studies and applications in catalytic hydrogenation of 1-alkenes and 4-alkenes (2002)

Wolf, E. De, Spek, A.L., Kuipers, B.W.M., Philipse, A.P., Meeldijk, J.D., Bomans, P.H.H., ...

Fluorous derivatives of 1,2-bis(diphenylphosphino)ethane (dppe) (1), containing a para-(1H,1H,2H,2H-perfluoroalkyl)silyl function, were used in the synthesis of fluorous derivatives of...

The synthesis and magnetic properties of nanosized hematite (a-Fe2O3) particles (2002)

Raming, T.P., Winnubst, A.J.A., Kats Van, C.M., Philipse, A.P.

The synthesis of nanosized superparamagnetic hematite particles by dissolving ferric salts in hydrochloric acid and heating at 100°C is described. A hydrolysis reaction causes the formation of...

Depletion-induced crystallization in colloidal rod-sphere mixtures (1999)

Koenderink, G.H., Vliegenthart, G.A., Blaaderen, A. Van, Philipse, A.P., Lekkerkerker, H.N.W.

We report the observation of depletion-induced phase separation in a mixture of colloidal silica spheres and colloidal silica rods with light microscopy and confocal scanning laser microscopy. We...

Preparation and properties of organic dispersions of monodisperse silica receptor colloids grafted with calixarene derivatives or alkyl chains (1996)

Nechifor, A.M., Philipse, A.P., Jong De, F., Egberink, R.J.M., Reinhoudt, D.N.

We introduce cation-selective receptor colloids consisting of a monodisperse inorganic silica core grafted with an organic layer containing calixarene receptor molecules. The surface layer is...

Phase behavior of aqueous dispersions of colloidal boehmite rods (1994)

Buining, P.A., Philipse, A.P., Lekkerkerker, H.N.W.

We report the phase behavior of aqueous dispersions containing rodlike boehmite particles with two different average lengths, 130 and 280 nm, with length-to-width ratios of approximately 8 and 20,...

Preparation of (non-)aqueous dispersins of colloidal boehmite needles (1993)

Buining, P.A., Pathmamanoharan, C., Philipse, A.P., Lekkerkerker, H.N.W.

A novel hydrothermal alkoxide method is presented for the preparation of stable, aqueousdispersions of fairly monodisperse, charged colloidal boehmite needles. A polymer coating procedure for the...

Preparation and properties of dispersions of colloidal boehmite rods (1993)

Buining, P.A., Philipse, A.P., Pathmamanoharan, C., Lekkerkerker, H.N.W.

Dispersions of colloidal boehmite (y-AlOOH) rods (of controllable length) are prepared from alkoxide precursors. A polyisobutene grafting procedure leads to sterically stabilized dispersions. In the...