E. V. Milsom

Probing Second Harmonic Components of pH-Sensitive Redox Processes in a Mesoporous TiO2-Nafion Film Electrode with Fourier-Transformed Large-Amplitude Sinusoidally Modulated Voltammetry (2009)

Milsom, E. V., Bond, A. M., O'Mullane, A. P., Elton, D., Lee, C. Y., Marken, Frank

Electrochemical processes in mesoporous TiO2-Nafion thin films deposited on indium tin oxide (ITO) electrodes are inherently complex and affected by capacitance, Ohmic iR-drop, RC-time constant...

Optical waveguide spectroscopy study of the transport and binding of cytochrome c in mesoporous titanium dioxide electrodes (2008)

Cameron, P. J., Jenkins, A. T. A., Knoll, Wolfgang, Marken, F., Milsom, E. V., Williams, T. L.

Layer-by-layer assembly of Ru3+ and Si8O208- into electrochemically active silicate films (2008)

Rassaei, L., Sillanpaa, M., Milsom, E. V., Zhang, X. H., Marken, F.

A porous silicate is obtained from octa-anionic Si8O208- cage-like poly-silicate (PS) and Ru3+ cations in an ethanol-based layer-by-layer assembly process. Electrochemical experiments (voltammetry...

Reactivity of methemoglobin immobilized on TiO2 nanoparticle films (2008)

Milsom, E. V., Dash, H. A., Jerikins, A. T. A., Opallo, M., Marken, F.

Facile demetallation occurs upon contact of the methemoglobin with a mesoporous TiO2 host in phosphate buffer media at pH 5.5 but not in acetate buffer media. As a result, voltammetric signals...

Assembly, conductivity, and chemical reactivity of sub-monolayer gold nanoparticle junction arrays (2008)

French, R. W., Milsom, E. V., Moskalenko, A. V., Gordeev, S. N., Marken, F.

Assemblies of gold nanoparticles (nominal 20 nm in diameter) and poly-(diallyldimethylammonium chloride) (PDDAC) are formed on tin-doped indium oxide (ITO) and glass substrates in a layer-by-layer...

Electrocatalytic oxidation of nitric oxide at TiO2-Au nanocomposite film electrodes (2007)

Milsom, E. V., Novak, J., Oyama, M., Marken, F.

Structured films of TiO2 (anatase) nanoparticles (ca. 6 nm diameter) and gold nanoparticles (nominal 20 nm diameter) are formed via a layer-by-layer deposition procedure. TiO2 nanoparticles are...

Layer-by-layer deposition of open-pore mesoporous TiO2-Nafion (R) film electrodes (2007)

Milsom, E. V., Novak, J., Green, S. J., Zhang, X. H., Stott, S. J., Mortimer, R. J., ...

The formation of variable thickness TiO2 nanoparticle-Nafion(R) composite films with open pores is demonstrated via a layer-by-layer deposition process. Films of about 6 nm diameter TiO2...

The effects of conductivity and electrochemical doping on the reduction of methemoglobin immobilized in nanoparticulate TiO2 films (2007)

Milsom, E. V., Dash, H. A., Jenkins, T. A., Opallo, M., Marken, F.

Methemoglobin (bovine) is immobilized from aqueous phosphate buffer (pH 5.5) solution into thin porous TiO2 (anatase) films at ITO electrode surfaces. Films of TiO2 are produced in a deposition...

SnO2-poly(diallyldimethylammonium chloride) films: Electrochemical evidence for heme protein absorption, denaturation, and demetallation (2007)

Milsom, E. V., Dash, H. A., Jenkins, T. A., Halliwell, C. M., Thetford, A., Bligh, N., ...

Thin mesoporous nanocomposite films of SnO2-poly(diallyidimethylammonium chloride) are formed in a layer-by-layer deposition process from SnO2 nanoparticles (nominal 15 nm diameter) and...

Demetallation of methemoglobin in cellulose nanofibril-TiO2 nanoparticle composite membrane electrodes (2007)

Bonne, M. J., Milsom, E. V., Helton, M., Thielemans, W., Wilkins, S., Marken, F.

Porous composite films containing cellulose nanofibrils (from sisal) and TiO2 nanoparticles (ca. 6 nm diameter) are obtained in a layer-by-layer assembly process. Each layer consists of ca. 0.18 mu g...

A novel cation-binding TiO2 nanotube substrate for electro- and bioelectro-catalysis (2005)

Bavykin, D.V., Milsom, E.V., Marken, F., Kim, D.H., Marsh, D.H., Riley, D.J., ...

TiO2 nanotubes (8–20 nm outer diameter and 3–5 nm inner diameter) grown via alkaline hydrothermal synthesis are characterised and compared to 6 nm diameter TiO2 (anatase) nanoparticles. Zeta...

A novel cation-binding TiO2 nanotube substrate for electro- and bioelectrocatalysis (2005)

Bavykin, D. V., Milsom, E. V., Marken, F., Kim, D. H., Marsh, D. H., Riley, D. J., ...

TiO2 nanotubes (8-20 nm outer diam. and 3-5 nm inner diam.) grown via alk. hydrothermal synthesis are characterized and compared to 6 nm diam. TiO2 (anatase) nanoparticles. Zeta potential,...

Redox processes in mesoporous oxide membranes: Layered TiO2 phytate and TiO2 flavin adenine dinucleotide films (2005)

Milsom, E. V., Perrott, H. R., Peter, L. M., Marken, F.

Thin films of TiO2 (anatase) nanoparticles are assembled at an electrode surface via a layer-by-layer deposition process employing phytic acid, pyromellitic acid, or flavin adenine dinucleotide (FAD)...

A novel cation-binding TiO2 nanotube substrate for electro-catalysis and bioelectro-catalysis (2005)

Bavykin, D. V., Milsom, E. V., Marken, F., Kim, D. H., Marsh, D. H., Riley, D. J., ...

TiO2 nanotubes (8-20 nm outer diameter and 3-5 nm inner diameter) grown via alkaline hydrothermal synthesis are characterised and compared to 6 nm diameter TiO2 (anatase) nanoparticles. Zeta...