A detailed investigation of the isotopic course of the reactions of uranium hydride with acids is described. The study was extended to include other oxidizing agents as well. Stoichiometry is a...
THE REACTIONS OF METAL OXIDES WITH CR()aq, (2006)
When Cr(ACTS WITH MnO2, PbO2, Tl2O3, Mn2O3, Co2O3, or CeO2, Cr(OH2)6(3) is in each case the predominant form of the Cr(III) product. When the oxidizing agent has a higher ratio of O (-)/Pb(IV), as...
TRACER EXPERIMENTS WITH OZONE AS OXIDIZING AGENT IN AQUEOUS SOLUTION, (2005)
Espenson,James H., Taube,Henry
When ozone reacts with sulfur dioxide in aqueous acid solution, as many as two ozone-oxygens appear in each product sulfate ion. Corresponding to this excess transfer (only one O being required for...
TRACER STUDIES ON THE OXIDATION OF PB(II) BY H202 (2005)
AGARWALA,U., ANBAR,M., TAUBE,HENRY
The major result obtained is that in the reaction of plumbite with H2O2, all of the O in the PbO2 part of the solid is derived from the oxidizing agent. The Pb(II) makes special use of the peroxide...
OXYGEN ATOM TRANSFER PROCESS (2005)
1. "Evidence for the Exchange of Hydroxyl Radical with Water": Reprinted from the Journal of the American Chemical Society, v74, p3705, 1952. 2. "The Photochemical Decomposition of Hydrogen Peroxide....
TRACER STUDIES ON THE OXIDATION OF UO2 IN ACIDIC AQUEOUS SOLUTION. (2005)
Experiments were done on the oxidation of UO2 in acidic solution. UO2() has been shown not to undergo rapid exchange of oxygen with the sol vent, at least when the concentration of U(V) is kept low....
Farquharson,Stuart, Weaver,Michael J., Lay,Peter A., Magnuson,Roy H., Taube,Henry
Surface-enhanced Raman scattering (SERS) has been observed for pentaamminepyridineosmium(III) adsorbed at a silver electrode as a function of electrode potential in order to examine the molecular...
Mechanisms of Oxidation with Oxygen
Several topics are dealt with in discussing the reactions of molecular oxygen, but a common goal is pursued in each: to try to understand the reactions in terms of the fundamental properties of the...