Miyashita, Seiji, Rikvold, Per Arne, Mori, Takashi, Konishi, Yusuké, Nishino, Masamichi, Tokoro, Hiroko
Photo-induced switching from the low-spin state to the high-spin state is studied in a model of spin-crossover materials, in which long-range interactions are induced by elastic distortions due to...
Poly[[hexa-μ-cyanido-manganese(II)iron(III)] pentahydrate] (2008)
Tomoyuki Matsuda, Hiroko Tokoro, Motoo Shiro, Kazuhito Hashimoto, Shin-ichi Ohkoshi
The structure of the title compound, MnII[FeIII(CN)6]2/3·5H2O, features a face-centered cubic –Mn—NC—Fe– framework with both Mn and Fe having site symmetry moverline{3}m....
Realization of the mean-field universality class in spin-crossover materials (2007)
Miyashita, Seiji, Konishi, Yusuké, Nishino, Masamichi, Tokoro, Hiroko, Rikvold, Per Arne
In spin-crossover materials, the volume of a molecule changes depending on whether it is in the high-spin (HS) or low-spin (LS) state. This change causes distortion of the lattice. Elastic...
Monte Carlo simulation of pressure-induced phase transitions in spin-crossover materials (2007)
Konishi, Yusuke, Tokoro, Hiroko, Nishino, Masamichi, Miyashita, Seiji
Pressure-induced phase transitions of spin-crossover materials were simulated by a Monte Carlo simulation in the constant pressure ensemble for the first time. Here, as the origin of the cooperative...
Photoinduced Magnetization in Copper Otacyanomolybdate (2006)
Ohkoshi, Shin-Ichi, Tokoro, Hiroko, Hozumi, Toshiya, Zhang, Yue, Hashimoto, Kazuhito, Mathonière, Corine, ...
This article describes the studies of a photomagnetic cyanide-bridged Cu-Mo bimetallic assembly, CuII2[MoIV(CN)8]·8H2O (CuII, S = 1/2; MoIV, S = 0) (1), which has an intervalence transfer (IT) band...
Structure of Metastable States in Phase Transitions with High-Spin Low-Spin Degree of Freedom (2005)
Miyashita, Seiji, Konishi, Yusuke, Tokoro, Hiroko, Nishino, Masamichi, Boukheddaden, Kamel, Varret, Francios
Difference of degeneracy of the low-spin (LS) and high-spin (HS) states causes interesting entropy effects on spin-crossover phase transitions and charge transfer phase transitions in materials...