Hue Sun Chan

A critical assessment of the topomer search model of protein folding using a continuum explicit-chain model with extensive conformational sampling (2005)

Wallin, Stefan, Chan, Hue Sun

Recently, a series of closely related theoretical constructs termed the “topomer search model” (TSM) has been proposed for the folding mechanism of small, single-domain proteins. A basic...

Energetics of Protein Thermodynamic Cooperativity: Contributions of Local and Nonlocal Interactions (2003)

Knott, Michael, Kaya, Huseyin, Chan, Hue Sun

The respective roles of local and nonlocal interactions in the thermodynamic cooperativity of proteins are investigated using continuum (off-lattice) native-centric G\=o-like models with a...

Contact Order Dependent Protein Folding Rates: Kinetic Consequences of a Cooperative Interplay Between Favorable Nonlocal Interactions and Local Conformational Preferences (2003)

Kaya, Huseyin, Chan, Hue Sun

Physical mechanisms underlying the empirical correlation between relative contact order (CO) and folding rate among naturally-occurring small single-domain proteins are investigated by evaluating...

Origins of Chevron Rollovers in Non-Two-State Protein Folding Kinetics (2003)

Kaya, Huseyin, Chan, Hue Sun

Chevron rollovers of some proteins imply that their logarithmic folding rates are nonlinear in native stability. This is predicted by lattice and continuum G\=o models to arise from diminished...

Simple Two-State Protein Folding Kinetics Requires Near-Levinthal Thermodynamic Cooperativity (2003)

Kaya, Huseyin, Chan, Hue Sun

Simple two-state folding kinetics of many small single-domain proteins are characterized by chevron plots with linear folding and unfolding arms consistent with a two-state description of equilibrium...

Solvation Effects and Driving Forces for Protein Thermodynamic And Kinetic Cooperativity: How Adequate Is Native-Centric Topological Modeling? (2002)

Kaya, Huseyin, Chan, Hue Sun

What energetic and solvation effects underlie the remarkable two-state thermodynamics and folding/unfolding kinetics of small single-domain proteins? To address this question, we investigate the...

Towards A Consistent Modeling Of Protein Thermodynamic And Kinetic Cooperativity: How Applicable Is The Transition State Picture To Folding and Unfolding? (2002)

Kaya, Huseyin, Chan, Hue Sun

To what extent do general features of folding/unfolding kinetics of small globular proteins follow from their thermodynamic properties? To address this question, we investigate a new simplifed...

Conformational propagation with prion-like characteristics in a simple model of protein folding (2001)

Harrison, Paul M., Chan, Hue Sun, Prusiner, Stanley B., Cohen, Fred E.

Protein refolding/misfolding to an alternative form plays an aetiologic role in many diseases in humans, including Alzheimer's disease, the systemic amyloidoses, and the prion diseases. Here we have...

Energetic Components of Cooperative Protein Folding (2000)

Kaya, Huseyin, Chan, Hue Sun

A new lattice protein model with a four-helix bundle ground state is analyzed by a parameter-space Monte Carlo histogram technique to evaluate the effects of an extensive variety of model potentials...

Polymer Principles of Protein Calorimetric Two-State Cooperativity (2000)

Kaya, Huseyin, Chan, Hue Sun

The experimental calorimetric two-state criterion requires the van't Hoff enthalpy $\Delta H_{\rm vH}$ around the folding/unfolding transition midpoint to be equal or very close to the calorimetric...

Designing amino acid sequences to fold with good hydrophobic cores (1995)

Sun, Shaojian, Brem, Rachel, Chan, Hue Sun, Dill, Ken A.

We present two methods for designing amino acid sequences of proteins that will fold to have good hydrophobic cores. Given the coordinates of the desired target protein or polymer structure, the...

Continuum regularization of gauge theory with fermions / (1987)

Chan, Hue Sun.

Thesis (Ph. D. in Physics)--University of California, Berkeley, May 1987.

Modeling evolutionary landscapes: Mutational stability, topology, and superfunnels in sequence space

Bornberg-Bauer, Erich, Chan, Hue Sun

Random mutations under neutral or near-neutral conditions are studied by considering plausible evolutionary trajectories on “neutral nets”—i.e., collections of sequences (genotypes)...

Recombinatoric exploration of novel folded structures: A heteropolymer-based model of protein evolutionary landscapes

Cui, Yan, Wong, Wing Hung, Bornberg-Bauer, Erich, Chan, Hue Sun

The role of recombination in evolution is compared with that of point mutations (substitutions) in the context of a simple, polymer physics-based model mapping between sequence (genotype) and...

Sparsely populated folding intermediates of the Fyn SH3 domain: Matching native-centric essential dynamics and experiment

Ollerenshaw, Jason E., Kaya, Hüseyin, Chan, Hue Sun, Kay, Lewis E.

A complete description of how a protein folds requires the characterization of intermediate conformations traversed during the folding transition. We have calculated dynamics trajectories of a...

Comparing Folding Codes in Simple Heteropolymer Models of Protein Evolutionary Landscape: Robustness of the Superfunnel Paradigm

Wroe, Richard, Bornberg-Bauer, Erich, Chan, Hue Sun

Understanding the evolution of biopolymers is a key element in rationalizing their structures and functions. Simple exact models (SEMs) are well-positioned to address general principles of evolution...

Chevron Behavior and Isostable Enthalpic Barriers in Protein Folding: Successes and Limitations of Simple Gō-like Modeling

Kaya, Hüseyin, Liu, Zhirong, Chan, Hue Sun

It has been demonstrated that a “near-Levinthal” cooperative mechanism, whereby the common Gō interaction scheme is augmented by an extra favorability for the native state as a whole, can lead...

Modeling evolutionary landscapes: Mutational stability, topology, and superfunnels in sequence space

Bornberg-Bauer, Erich, Chan, Hue Sun

Random mutations under neutral or near-neutral conditions are studied by considering plausible evolutionary trajectories on “neutral nets”—i.e., collections of sequences (genotypes)...

Recombinatoric exploration of novel folded structures: A heteropolymer-based model of protein evolutionary landscapes

Cui, Yan, Wong, Wing Hung, Bornberg-Bauer, Erich, Chan, Hue Sun

The role of recombination in evolution is compared with that of point mutations (substitutions) in the context of a simple, polymer physics-based model mapping between sequence (genotype) and...

Sparsely populated folding intermediates of the Fyn SH3 domain: Matching native-centric essential dynamics and experiment

Ollerenshaw, Jason E., Kaya, Hüseyin, Chan, Hue Sun, Kay, Lewis E.

A complete description of how a protein folds requires the characterization of intermediate conformations traversed during the folding transition. We have calculated dynamics trajectories of a...

Comparing Folding Codes in Simple Heteropolymer Models of Protein Evolutionary Landscape: Robustness of the Superfunnel Paradigm

Wroe, Richard, Bornberg-Bauer, Erich, Chan, Hue Sun

Understanding the evolution of biopolymers is a key element in rationalizing their structures and functions. Simple exact models (SEMs) are well-positioned to address general principles of evolution...

Chevron Behavior and Isostable Enthalpic Barriers in Protein Folding: Successes and Limitations of Simple Gō-like Modeling

Kaya, Hüseyin, Liu, Zhirong, Chan, Hue Sun

It has been demonstrated that a “near-Levinthal” cooperative mechanism, whereby the common Gō interaction scheme is augmented by an extra favorability for the native state as a whole, can lead...

Inferring Global Topology from Local Juxtaposition Geometry: Interlinking Polymer Rings and Ramifications for Topoisomerase Action

Liu, Zhirong, Zechiedrich, E. Lynn, Chan, Hue Sun

Lattice modeling is applied to investigate how the configurations of local chain juxtapositions may provide information about whether two ring polymers (loops) are topologically linked globally....

Hydrophobic association of α-helices, steric dewetting, and enthalpic barriers to protein folding

MacCallum, Justin L., Moghaddam, Maria Sabaye, Chan, Hue Sun, Tieleman, D. Peter

Efficient protein folding implies a microscopic funnel-like multidimensional free-energy landscape. Macroscopically, conformational entropy reduction can manifest itself as part of an empirical...

Polyelectrostatic interactions of disordered ligands suggest a physical basis for ultrasensitivity

Borg, Mikael, Mittag, Tanja, Pawson, Tony, Tyers, Mike, Forman-Kay, Julie D., Chan, Hue Sun

Regulation of biological processes often involves phosphorylation of intrinsically disordered protein regions, thereby modulating protein interactions. Initiation of DNA replication in yeast requires...

A critical assessment of the topomer search model of protein folding using a continuum explicit-chain model with extensive conformational sampling

Wallin, Stefan, Chan, Hue Sun

Recently, a series of closely related theoretical constructs termed the “topomer search model” (TSM) has been proposed for the folding mechanism of small, single-domain proteins. A basic...

Conformational propagation with prion-like characteristics in a simple model of protein folding

Harrison, Paul M., Chan, Hue Sun, Prusiner, Stanley B., Cohen, Fred E.

Protein refolding/misfolding to an alternative form plays an aetiologic role in many diseases in humans, including Alzheimer's disease, the systemic amyloidoses, and the prion diseases. Here we have...

Theoretical and experimental demonstration of the importance of specific nonnative interactions in protein folding

Zarrine-Afsar, Arash, Wallin, Stefan, Neculai, A. Mirela, Neudecker, Philipp, Howell, P. Lynne, Davidson, Alan R., ...

Many experimental and theoretical studies have suggested a significant role for nonnative interactions in protein folding pathways, but the energetic contributions of these interactions are not well...

The why and how of DNA unlinking

Liu, Zhirong, Deibler, Richard W., Chan, Hue Sun, Zechiedrich, Lynn

The nucleotide sequence of DNA is the repository of hereditary information. Yet, it is now clear that the DNA itself plays an active role in regulating the ability of the cell to extract its...

A structural model of latent evolutionary potentials underlying neutral networks in proteins

Wroe, Richard, Chan, Hue Sun, Bornberg-Bauer, Erich

A central question in molecular evolution concerns the nature of phenotypic transitions, in particular, if neutral mutations hamper or somehow facilitate adaptability of proteins to new requirements....

Liaison amid disorder: non-native interactions may underpin long-range coupling in proteins

Chan, Hue Sun, Zhang, Zhuqing

A lattice-model study of double-mutant cycles published in BMC Structural Biology underscores how interactions in non-native conformations can lead to thermodynamic coupling between distant residues...