Polar three-arm star block copolymer thermoplastic elastomers based on polyacrylonitrile (2008)
Dufour, B., Tang, C. B., Koynov, Kaloian, Zhang, Y., Pakula, Tadeusz, Matyjaszewski, K.
Viscoelastic and dielectric studies on comb- and brush-shaped poly(n-butyl acrylate) (2008)
Berry, G. C., Kahle, S., Ohno, S., Matyjaszewski, K., Pakula, Tadeusz
PBA-PMMA 3-arm star block copolymer thermoplastic elastomers (2008)
Dufour, B., Koynov, Kaloian, Pakula, Tadeusz, Matyjaszewski, K.
Cypryk, M., Chrusciel, J., Fossum, E., Matyjaszewski, K.
Ring-opening polymerization of cyclic silanes is described as a new synthetic route to well defined high molecular weight polysilylenes (polysilanes). Strained cyclotetrasilanes with phenyl and...
Molecular brushes as super-soft elastomers (2006)
Pakula, Tadeusz, Zhang, Y., Matyjaszewski, K., Lee, H. I., Boerner, H., Qin, S. H., ...
On the shape of bottle-brush macromolecules: Systematic variation of architectural parameters (2005)
Rathgeber,S., Pakula,Tadeusz, Wilk,A., Matyjaszewski,K., Beers,K. L.
Mignard, E., Leblanc, T., Matyjaszewski, K., Guerret, O., Reed, W.F.
Homogeneous bulk atom transfer radical polymerization (ATRP) of n-butyl acrylate (BA) was monitored by automatic continuous online monitoring of polymerization reactions (ACOMP). This allowed...
On the shape of bottle-brush macromolecules: Systematic variation of architectural parameters (2005)
Rathgeber, S., Pakula, Tadeusz, Wilk, A., Matyjaszewski, K., Beers, K. L.
PDMS-PEO densely grafted copolymers (2005)
Neugebauer, D., Zhang, Y., Pakula, Tadeusz, Matyjaszewski, K.
On the shape of bottle-brush macromolecules: Systematic variation of architectural parameters (2005)
Rathgeber, S., Pakula, T., Wilk, A., Matyjaszewski, K., Beers, K. L.
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Super soft elastomers as ionic conductors (2004)
Ying,Z., Costantini,N., Mierzwa,M., Pakula,Tadeusz, Neugebauer,D., Matyjaszewski,K.
Super soft elastomers as ionic conductors (2004)
Ying, Z., Costantini, N., Mierzwa, M., Pakula, Tadeusz, Neugebauer, D., Matyjaszewski, K.
Heterografted PEO-PnBA brush copolymers (2003)
Neugebauer,D., Zhang,Y., Pakula,Tadeusz, Matyjaszewski,K.
A series of P[(HEMA-TMS)-co-PEOMA] graft copolymers with different amounts of incorporated macromonomer grafts were prepared by copolymerization of a PEO macromonomer (PEOMA, MWav = 1100 g/mol, DPPEO...
Densely-grafted and double-grafted PEO brushes via ATRP. A route to soft elastomers (2003)
Neugebauer,D., Zhang,Y., Pakula,Tadeusz, Sheiko,S. S., Matyjaszewski,K.
Two macromonomers containing ethylene oxide (EO) segments with different degrees of polymerization (DPPEO = 5 and 23), capped by a methoxy and a methacrylate group (PEOMA), were polymerized by atom...
Shinoda,H., Matyjaszewski,K., Okrasa,L., Mierzwa,M., Pakula,Tadeusz
Atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) process, and the conventional radical polymerization (RP) were applied to the copolymerization of...
Pakula,Tadeusz, Minkin,P., Matyjaszewski,K.
In this chapter, we discuss problems related to the synthesis, structure and dynamic behavior of macromolecular systems, in which many linear chains are anchored to other macromolecules, to...
Lutz,J. F., Pakula,Tadeusz, Matyjaszewski,K.
The control of the overall composition and the sequence distribution in copolymers with both linear and branched architectures is described. The synthesis of alternating and gradient copolymers as...
Pakula, Tadeusz, Minkin, P., Matyjaszewski, K.
In this chapter, we discuss problems related to the synthesis, structure and dynamic behavior of macromolecular systems, in which many linear chains are anchored to other macromolecules, to...
Lutz, J. F., Pakula, Tadeusz, Matyjaszewski, K.
The control of the overall composition and the sequence distribution in copolymers with both linear and branched architectures is described. The synthesis of alternating and gradient copolymers as...
Shinoda, H., Matyjaszewski, K., Okrasa, L., Mierzwa, M., Pakula, Tadeusz
Atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) process, and the conventional radical polymerization (RP) were applied to the copolymerization of...
Densely-grafted and double-grafted PEO brushes via ATRP. A route to soft elastomers (2003)
Neugebauer, D., Zhang, Y., Pakula, Tadeusz, Sheiko, S. S., Matyjaszewski, K.
Two macromonomers containing ethylene oxide (EO) segments with different degrees of polymerization (DPPEO = 5 and 23), capped by a methoxy and a methacrylate group (PEOMA), were polymerized by atom...
Heterografted PEO-PnBA brush copolymers (2003)
Neugebauer, D., Zhang, Y., Pakula, Tadeusz, Matyjaszewski, K.
A series of P[(HEMA-TMS)-co-PEOMA] graft copolymers with different amounts of incorporated macromonomer grafts were prepared by copolymerization of a PEO macromonomer (PEOMA, MWav = 1100 g/mol, DPPEO...
Gradient Copolymers by Atom Transfer Radical Copolymerization (2000)
Matyjaszewski, K., Ziegler, M. J., Arehart, S. V., Greszta, D., Pakula, Tadeusz
Homopolymerization and Copolymerization of Alkenyldichlorosilanes by Reductive Coupling. (1998)
Sonochemical reductive coupling of dichlorosilanes containing allyl and 5-hexenyl group leads to the formation of high molecular weight polymers and oligomeric fractions. Both products contain...
Mechanism of the initiation of the cationic polymerization of styrenes by silanes and activated covalent species has been studied by NMR and SEC. Trimethylsilyl trifluoromethanesulfonate has been...
Unimolecular and Bimoleculare Exchange Reactiions in Controlled Radical Polymerization. (1998)
Matyjaszewski, K., Gaynor, S., Greszta, D., Mardare, D., Shigemoto, T.
Well defined polymers can be produced by radical polymerization using three different approaches: degenerative, transfer, reversible homolytic cleavage of covalent species, and reversible homolytic...
Matyjaszewski, K., Fossum, E., Love, J. A.
Polystyrene/poly(methylphenylsilylene) and polyisoprene/poly(methylphenyl silylene) block copolymers were prepared by two independent methods. Subsequent additions of solutions of cyclotetrasilanes...
Modifications of Polysilanes and Polysilane Copolymers. (1998)
Poly(methylphenylsilylene)has been functionalized by protodearylation with trifluoromethanesulfonic acid. Comb-like graft copolymers have been prepared by polymerizing tetrahydrofuran,...
Ring Opening Polymerization of Cyclotetrasilanes: A Versatile Route to Linear Polysilylenes. (1998)
This paper reviews ring opening polymerization (ROP) of cyclotetrasilanes. The ROP of cyclotetrasilanes is an interesting and versatile method to prepare both polysilylenes homo and copolymers which...
Matyjaszewski, K., Gaynor, S. G., Wang, J. S.
Through alkyl iodides, R' - X, used as degenerative transfer agents, control of the radical polymerization of styrene and butyl acrylate has been achieved. The polymerizations were initiated by AIBN...
Fundamentals and Practical Aspects of 'Living' Radical Polymerization. (1998)
Fundamentals and some practical synthetic aspects of controlled radical polymerization will be discussed in the lecture. Effect of slow initiation, termination, and transfer on kinetics, molecular...
Polysilane-Poly(Ferrocenylsilane) Random Copolymers. (1998)
Matyjaszewski, K., Fossum, E., Rulkens, R., Manners, I.
Thermal polymerization of ferrocenyldimethylsilane with tetramethyltetraphenyltetracyclosilane was carried out at various ratios of the comonomers. The exact composition of copolymers depends on the...
Controlled/'Living' radical polymerization allows for the preparation of complex polymer architectures, end functional polymers and block copolymers. Recently, we reported atom transfer radical...
Kinetic Studies of Atom Transfer Radical Polymerization of Methyl Acrylate. (1998)
Kinetic aspects of Atom Transfer Radical Polymerization of methyl acrylate MA were studied. The results showed the characteristic features of living polymerization up to Mn (80,000, e.g. constant...
Controlled Radical Polymerization with Dendrimers Containing Stable Radicals. (1998)
Shigemoto, T., Matyjaszewski, K., Leduc, M., Frechet, J. M.
TEMPO-based stable radicals were attached to dendrimers of variable size and used to control radical polymerization of styrene, vinyl acetate and (meth)acrylates. Thermal polymerization of styrene...
Structures and chirooptical properties of optically active poly(dipentylsilylene) copolymers (1995)
Frey, H.H., Moller, M., Turetski, A., Lotz, B., Matyjaszewski, K.