M. A. Paver

Organo-functionalised arsine and stibine organometallics; syntheses and structural characterisations of 1,3- (PhC C)(2)Sb (2)(CH2)(3), As(C CPh)(3), R2AsCH2AsR2 R = Me3SiC C-, (Me3Si)(2)N- and 2-SPy with pi-stacking in the latter (2003)

Paver, M.A., Joy, J.S., Coles, S.J., Hursthouse, M.B., Davies, J.E.

A series of dinuclear organo-functionalised stibine and arsine ligands incorporating a range of hard, soft and pi-donor moieties have been synthesised from the reactions of Cl2Sb(CH2)(3)SbCl2 and...

A twenty-four membered mixed-metal macrocycle; synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6 (2002)

Paver, M.A., Joy, J.S., Hursthouse, M.B.

The first example of a twenty-four membered mixed p-/s-block macrocycle, cyclo-[(3-Me-1,2-C6H3O2)(2)SbNa(THF)(2)](6) 1 has been synthesised and structurally characterised from the reaction between...

2,2-bis(chloromethyl)propylene bis(diphenylstibine) (2001)

Coles, S. J., Hursthouse, M. B., Joy, J. S., Paver, M. A.

The title compound, [Sb-2(C6H5)(4)(C5H8Cl2)], is the product of a substitution reaction of 2,2-bis(chloromethyl)-1,3-dichloropropane with sodium diphenylstibide. Adjacent phenyl groups embrace each...

bis(bis(2-Pyridylthio)arsino)methane (2001)

Davies, J. E., Hursthouse, Michael B., Coles, Simon J., Joy, J. S., Paver, M. A.

bis(bis(2-Pyridylthio)arsino)methane (2001)

Paver, M. A., Joy, J. S., Coles, S. J., Hursthouse, M. B., Davies, J. E.

meso-Octacyclopropylcalix[4]pyrrole ethanol solvate (2001)

Camiolo, S., Coles, S.J., Gale, P.A., Hursthouse, M.B., Paver, M.A.

The title compound, C44H52N4·C2H5OH, is a calix[4]pyrrole-type macrocycle acting as a receptor, by means of hydrogen-bond interactions to an ethanol solvent. The pyrrole groups are arranged in a...

The first example of a diazaarsolyl anion: structure and coordination polymerisation of the aromatic metallacycle benzo[1,3,2]diazaarsolyl lithium.2THF (2001)

Paver, M.A., Joy, J.S., Hursthouse, M.B.

The first example of an aromatic diazaarsolyl anion 1 has been synthesised and structurally characterised; the X-ray crystal structure of 1 exhibits planar metallacyclic fragments which link together...

A novel chiral distibine-centred polyimido anion (2000)

Coles, S. J., Hursthouse, M. B., Joy, J. S., Paver, M. A.

Reaction of (Me2N)(2)Sb(CH2)(3)Sb(NMe2)(2) with 4 equivalents of 2-NHLiPy (Py = pyridyl) generates the novel distibine-centred dianion complex 1,3-[(RNLi)Sb](2)(mu-NR)(CH2)(3).(RNHLi). 3THF (1),...

Hydrogen bonding networks and anion coordination in (eta(6)-arene)Cr(CO)(3) complexes: metal carbonyls as hydrogen bond acceptors (2000)

Camiolo, S., Coles, S. J., Gale, P. A., Hursthouse, M. B., Mayer, T. A., Paver, M. A.

A chloride selective amide cleft molecule 2 containing two Cr(CO)(3) moieties has been synthesised by condensation of (eta(6)-aniline)Cr(CO)(3) 3 with isophthaloyl dichloride; the X-ray crystal...