Toward a more general solution to the band-broadening problem in size separation of polymers (2007)
Konkolewicz, D., Taylor, J. W., Castignolles, P., Gray-Weale, A., Gilbert, R. G.
The molecular weight distributions (MWDs) and hydrodynamic volume distributions of polymers can reveal considerable mechanistic information on the polymerization process, and have significant effects...
Grafting of oligosaccharides onto synthetic polymer colloids (2007)
Mange, S., Dever, C., De Bruyn, H., Gaborieau, M., Castignolles, P., Gilbert, R. G.
A new method to form colloidally stable oligosaccharide-grafted synthetic polymer particles has been developed. The oligosaccharides, of weight-average degree of polymerization similar to 38, were...
High-resolution separation of oligo(acrylic acid) by capillary zone electrophoresis (2006)
Castignolles, P., Gaborieau, M., Hilder, E. F., Sprong, E., Ferguson, C. J., Gilbert, R. G.
Oligo(acrylic acid)s, produced by RAFT polymerization, have been separated and analyzed for the first time by capillary zone electrophoresis. The resolution obtained by capillary electrophoresis in...
Asua, J. M., Beuermann, S., Buback, M., Castignolles, P., Charleux, B., Gilbert, R. G., ...
Propagation rate coefficients, k(P), for free-radical polymerization of butyl acrylate (BA) previously reported by several groups are critically evaluated. All data were determined by the combination...