Philippe Gerbier

Molecular engineering to improve the charge carrier balance in single-layer silole-based OLEDs (2009)

Aubouy, Laurent, Huby, Nolwenn, Hirsch, Lionel, Van Der Lee, Arie, Gerbier, Philippe

We report a molecular engineering study on optical, structural and electrical properties of seven silole derivates aimed at enhancing the charge carrier balance in single-layer devices. By...

Molecular engineering to improve the charge carrier balance in single-layer silole-based OLEDs (2009)

Aubouy, Laurent, Huby, Nolwenn, Hirsch, Lionel, Van Der Lee, Arie, Gerbier, Philippe

We report a molecular engineering study on optical, structural and electrical properties of seven silole derivates aimed at enhancing the charge carrier balance in single-layer devices. By...

Evidence of environmental strains on charge injection in silole based organic light emitting diodes (2007)

Huby, Nolwenn, Hirsch, Lionel, Aubouy, Laurent, Gerbier, Philippe, Van Der Lee, Arie, Amy, Fabrice, ...

Using d. functional theory (DFT) computations, the authors demonstrated a substantial skeletal relaxation when the structure of 2,5-bis-[4-anthracene-9-yl-phenyl]-1,1-dimethyl-3,4-diphenyl-silole...

Study of the influence of the molecular organization on single-layer OLEDs' performances (2007)

Aubouy, Laurent, Gerbier, Philippe, Guérin, Christian, Huby, Nolwenn, Hirsch, Lionel, Vignau, Laurence

The authors synthesized three new silole derivs. with incrementally flexible structure to tune their packing ability and therefore study the influence of the mol. organization in single-layer OLEDs....

Study of the influence of the molecular organization on single-layer OLEDs' performances. (2007)

Aubouy, Laurent, Gerbier, Philippe, Guérin, Christian, Huby, Nolwenn, Hirsch, Lionel, Vignau, Laurence

The authors synthesized three new silole derivs. with incrementally flexible structure to tune their packing ability and therefore study the influence of the mol. organization in single-layer OLEDs....

New insights into ligand inductive effects on the stability of Mn12 single molecule magnets. Synthesis, magnetic and thermal characterization of complex [Mn12O12(O2CC≡CH)16(H2O)4].3H2O and the corresponding manganese(II) propiolate [Mn3(O2CC≡CH)6(H2O)4]2H2O derived by thermolysis reaction. (2007)

Gómez-Segura, Jordi, Campo, Javier, Imaz, Inhar, Wurst, Klaus, Veciana, Jaume, Gerbier, Philippe, ...

Two novel Mn12 derivs., [Mn12O12(O2CCCH)16(H2O)4].3H2O (1) and [Mn12O12(O2CCCC6H5)16(H2O)4].3H2O (2) were prepd. and characterized. Magnetic measurements confirm that both function as single-mol....

Evidence of environmental strains on charge injection in silole based organic light emitting diodes. (2007)

Huby, Nolwenn, Hirsch, Lionel, Aubouy, Laurent, Gerbier, Philippe, Van Der Lee, Arie, Amy, Fabrice, ...

Using d. functional theory (DFT) computations, the authors demonstrated a substantial skeletal relaxation when the structure of 2,5-bis-[4-anthracene-9-yl-phenyl]-1,1-dimethyl-3,4-diphenyl-silole...

Study of the influence of the molecular organization on single-layer OLEDs' performances. (2007)

Aubouy, Laurent, Gerbier, Philippe, Guérin, Christian, Huby, Nolwenn, Hirsch, Lionel, Vignau, Laurence

The authors synthesized three new silole derivs. with incrementally flexible structure to tune their packing ability and therefore study the influence of the mol. organization in single-layer OLEDs....

New insights into ligand inductive effects on the stability of Mn12 single molecule magnets. Synthesis, magnetic and thermal characterization of complex [Mn12O12(O2CC≡CH)16(H2O)4].3H2O and the corresponding manganese(II) propiolate [Mn3(O2CC≡CH)6(H2O)4]2H2O derived by thermolysis reaction. (2007)

Gómez-Segura, Jordi, Campo, Javier, Imaz, Inhar, Wurst, Klaus, Veciana, Jaume, Gerbier, Philippe, ...

Two novel Mn12 derivs., [Mn12O12(O2CCCH)16(H2O)4].3H2O (1) and [Mn12O12(O2CCCC6H5)16(H2O)4].3H2O (2) were prepd. and characterized. Magnetic measurements confirm that both function as single-mol....

Evidence of environmental strains on charge injection in silole based organic light emitting diodes. (2007)

Huby, Nolwenn, Hirsch, Lionel, Aubouy, Laurent, Gerbier, Philippe, Van Der Lee, Arie, Amy, Fabrice, ...

Using d. functional theory (DFT) computations, the authors demonstrated a substantial skeletal relaxation when the structure of 2,5-bis-[4-anthracene-9-yl-phenyl]-1,1-dimethyl-3,4-diphenyl-silole...

Towards a Better Understanding of Photo-excited Spin Alignment Processes Using Silole Diradicals. (2006)

Roques, Nans, Gerbier, Philippe, Teki, Yoshio, Choua, Sylvie, Lesniakova, Petra, Sutter, Jean-Pascal, ...

Stable bis-nitroxide diradicals I (TPSNN, X = O-; TPSIN, X and charge absent), conjugated with silole moiety via 1,4-phenylene groups, were prepd. by reductive cyclization of Me2Si(C.tplbond.CPh)2...

Organic Light-emitting Diodes and Organic Light-emitting Electrochemical Cells Based on Silole-Fluorene Derivatives. (2006)

Habrard, Florian, Ouisse, T., Stephan, O., Aubouy, Laurent, Gerbier, Philippe, Hirsch, Lionel, ...

ilole groups are known to present a high electron affinity. Initially, copolymn. of siloles with fluorene was aimed at improving electron injection into the polymer layer and so improving the...

Experimental and Theoretical Studies on Magnetic Exchange in Silole-Bridged Diradicals. (2006)

Roques, Nans, Gerbier, Philippe, Schatzschneider, Ulrich, Sutter, Jean-Pascal, Guionneau, Philippe, Vidal-Gancedo, Jose, ...

Five bis(tert-butylnitroxide) diradicals connected by a silole [2,5-R2-3,4-diphenylsilole; R = Me3CN(®O.bul.)Z; Z = p-C6H4 (7a), p-C6H4C6H4-p (7b), 1,4-naphthalenediyl (7c), m-C6H4 (7d)] or a...

Injection and transport processes in organic light emitting diodes based on a silole derivative. (2006)

Huby, Nolwenn, Wantz, Guillaume, Hirsch, Lionel, Vignau, Laurence, Barriere, A.S., Aubouy, Laurent, ...

This paper reports on charge injection and transport in electroluminescent devices based on a silole deriv. 1,1-dimethyl-2,5-bis(p-2,2'-dipyridylaminophenyl)-3,4-diphenylsilole (DMPPS). The devices...

Bis(hexafluoroacetylacetonato)manganese(II) complex of 1,1-dimethyl-2,5-bis-(3-N-tert-butyl-N-phenylaminoxyl) -3,4-diphenylsilolacyclopentadiene. (2006)

Roques, Nans, Gerbier, Philippe, Imaz, Inhar, Guionneau, Philippe, Sutter, Jean-Pascal

Crystals of the 1st bis-adduct of 2,5-bis[3-(tert-butylaminoxyl)phenyl]-1,1-dimethyl-3,4-diphenylsilole with bis(hexafluoroacetylacetonato)manganese(II) are monoclinic, space group P21/n; Z = 2. The...

Silole derivatives: relationships between molecular arrangement and OLED efficiency. (2006)

Gerbier, Philippe, Aubouy, Laurent, Huby, Nolwenn, Hirsch, Lionel, Vignau, Laurence

The goal of the present study is to underline the relationships that may exist between the molecular arrangement in thin films and the OLED efficiency. For this purpose, we have synthesized three new...

Experimental and Theoretical Studies on Magnetic Exchange in Silole-Bridged Diradicals. (2006)

Roques, Nans, Gerbier, Philippe, Schatzschneider, Ulrich, Sutter, Jean-Pascal, Guionneau, Philippe, Vidal-Gancedo, Jose, ...

Five bis(tert-butylnitroxide) diradicals connected by a silole [2,5-R2-3,4-diphenylsilole; R = Me3CN(®O.bul.)Z; Z = p-C6H4 (7a), p-C6H4C6H4-p (7b), 1,4-naphthalenediyl (7c), m-C6H4 (7d)] or a...

Bis(hexafluoroacetylacetonato)manganese(II) complex of 1,1-dimethyl-2,5-bis-(3-N-tert-butyl-N-phenylaminoxyl) -3,4-diphenylsilolacyclopentadiene. (2006)

Roques, Nans, Gerbier, Philippe, Imaz, Inhar, Guionneau, Philippe, Sutter, Jean-Pascal

Crystals of the 1st bis-adduct of 2,5-bis[3-(tert-butylaminoxyl)phenyl]-1,1-dimethyl-3,4-diphenylsilole with bis(hexafluoroacetylacetonato)manganese(II) are monoclinic, space group P21/n; Z = 2. The...

Towards a Better Understanding of Photo-excited Spin Alignment Processes Using Silole Diradicals. (2006)

Roques, Nans, Gerbier, Philippe, Teki, Yoshio, Choua, Sylvie, Lesniakova, Petra, Sutter, Jean-Pascal, ...

Stable bis-nitroxide diradicals I (TPSNN, X = O-; TPSIN, X and charge absent), conjugated with silole moiety via 1,4-phenylene groups, were prepd. by reductive cyclization of Me2Si(C.tplbond.CPh)2...

Silole derivatives: relationships between molecular arrangement and OLED efficiency. (2006)

Gerbier, Philippe, Aubouy, Laurent, Huby, Nolwenn, Hirsch, Lionel, Vignau, Laurence

The goal of the present study is to underline the relationships that may exist between the molecular arrangement in thin films and the OLED efficiency. For this purpose, we have synthesized three new...

Organic Light-emitting Diodes and Organic Light-emitting Electrochemical Cells Based on Silole-Fluorene Derivatives. (2006)

Habrard, Florian, Ouisse, T., Stephan, O., Aubouy, Laurent, Gerbier, Philippe, Hirsch, Lionel, ...

ilole groups are known to present a high electron affinity. Initially, copolymn. of siloles with fluorene was aimed at improving electron injection into the polymer layer and so improving the...

Injection and transport processes in organic light emitting diodes based on a silole derivative. (2006)

Huby, Nolwenn, Wantz, Guillaume, Hirsch, Lionel, Vignau, Laurence, Barriere, A.S., Aubouy, Laurent, ...

This paper reports on charge injection and transport in electroluminescent devices based on a silole deriv. 1,1-dimethyl-2,5-bis(p-2,2'-dipyridylaminophenyl)-3,4-diphenylsilole (DMPPS). The devices...