Real-Time Control of a Catalytic Solid in a Fixed-Bed Reactor Based on In Situ Spectroscopy (2007)
Bennici, S.M., Vogelaar, B.M., Nijhuis, T.A., Weckhuysen, B.M.
Propene epoxidation over Au/Ti-SBA-15 catalysts (2007)
Sacaliuc, E., Beale, A.M., Weckhuysen, B.M., Nijhuis, T.A.
Highly dispersed gold nanoparticles were synthesized within the channels of a mesoporous Ti-SBA-15 support, followed by thorough catalyst characterization and testing in the selective epoxidation of...
Promotion Effects in the Oxidation of CO over Zeolite-Supported Pt Nanoparticles (2005)
Visser, T., Nijhuis, T.A., Jenken, K., Ji, Y., Bras, W., ...
Weckhuysen, B.M., Nijhuis, T.A., Tinnemans, S.J., Visser, T.
UV–Vis and Raman spectroscopy are applied under realistic reaction conditions to investigate the changes occurring to an industrial-like supported chromium oxide catalyst during the dehydrogenation...
Hoek, I., Nijhuis, T.A., Stankiewicz, A.I., Moulijn, J.A
The etherification of 1-octanol catalysed by zeolite BEA was investigated. The kinetics were determined in an open system with almost no water present. The influence of the catalyst particle size,...
Performance of the monolithic stirrer reactor: applicability in multi-phase processes (2004)
Hoek, I., Nijhuis, T.A., Stankiewicz, A.I., Moulijn, J.A
The novel monolithic stirrer reactor is a promising replacement for a conventional slurry reactor in multi-phase reactions. In this reactor monolithic structures are used as stirrer blades, creating...
Koten, G. Van, Nijhuis, T.A., Moulijn, J.A.
Silica-supported palladium catalysts for the selective liquid-phase hydrogenation of alkynes to alkenes were prepared. As a model reaction the hydrogenation of 3-methyl-1-pentyn-3-ol was chosen. The...
Nijhuis, T.A., Koten, G. Van, Moulijn, J.A.
A kinetic study has been made into the hydrogenation of 3-methyl-1-pentyn-3-ol over palladium on silica catalysts. This reaction already proceeds at very high rates under mild reaction conditions...
BEA coating of structured support - performance in acylation (2003)
Beers, A.E.W., Nijhuis, T.A., Aalders, N., Kapteijn, F., Moulijn, J.A
Nijhuis, T.A., Tinnemans, S.J., Visser, T., Weckhuysen, B.M.
A novel experimental set-up for characterizing supported metal oxide catalysts under working conditions has been developed. The set-up combines product analysis using on-line mass spectrometry (MS)...
Modeling of monolithic and trickle-bed reactors for the hydrogenation of styrene (2003)
Nijhuis, T.A., Dautzenberg, F.M., Moulijn, J.A
A kinetic study into the styrene hydrogenation over a palladium on alumina catalyst has been made. Styrene was used as a model component for pyrolysis gasoline. A kinetic rate expression has been...