1,4,7,10 - Tetraazacyclododecane Metal Complexes as Potent Promoters of Phosphodiester Hydrolysis under Physiologica (2008)
Subat, M.,
Woinaroschy, K.,
Gerstl, C.,
Sarkar, B.,
Kaim, W.,
König, B.
Mixed-valent and radical states of complexes [(bpy)2M(μ-abpy)M'(bpy)2]n+, M,M' = Ru or Os, abpy = 2,2'-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexes (2006)
Hellmann, M.,
Frantz, S.,
Kaim, W.,
Fiedler, J.,
Duboc, C.
The title complexes were obtained as (MM)-M-II'(II) species [(bpy)(2)M'(mu-abpy)M'(bpy)(2)](PF6)(4), M,M' = Ru or Os, using the new mononuclear precursor [(bPY)(2)Os(abpy)](PF6)(2) for the...
The redox series [M(bpy)2(Q)]n+, M=Ru or Os, Q=3,5-di-tert-butyl-N-phenyl-1,2-benzoquinonemonoimine. Isolation and a complete X and W band EPR study of the semiquinone states (n=1) (2005)
Ye, S. F.,
Sarkar, B.,
Duboc, C.,
Fiedler, J.,
Kaim, W.
Mechanism and product characterization from the electroreduction of heterodinuclear complexes [(C5Me5)ClM(μ-L)Re(CO)3X](PF6), M = Rh or Ir, L = 2,2'-azobispyridine or 2,2'-azobis(5-chloropyrimidine), X = halide (2004)
Frantz, S.,
Weber, M.,
Scheiring, T.,
Fiedler, J.,
Duboc, C.,
Kaim, W.
Complexes of [Re(CO)3Cl] with different oxidation states of the polyfunctional bmtz/H(2)bmtz ligand system (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine) (2004)
Frantz, S.,
Kaim, W.,
Fiedler, J.,
Duboc, C.
High-frequency EPR study of reduced diruthenium and dirhenium polypyridine complexes based on the 1,2,4,5-tetrazine radical bridge (2004)
Sarkar, B.,
Frantz, S.,
Kaim, W.,
Duboc, C.
First crystal structure determination and high-frequency EPR study of an organoarsanecopper radical complex (2003)
Ye, S. F.,
Kaim, W.,
Sarkar, B.,
Schwederski, B.,
Lissner, F.,
Schleid, T.,
...
Azo compounds as electron acceptor or radical ligands in transition metal species: spectroelectrochemistry and high-field EPR studies of ruthenium, rhodium and copper complexes of 2,2'-azobis(5-chloropyrimidine) (2003)
Kaim, W.,
Doslik, N.,
Frantz, S.,
Sixt, T.,
Wanner, M.,
Baumann, F.,
...
Multistep redox sequences of azopyridyl (L) bridged reaction centres in stable radical complex ions {(μL)[MCl(ξ5)-C5Me5)]2}·+), M = Rh or Ir: spectroelectrochemistry and high-frequency EPR spectroscopy (2003)
Frantz, S.,
Reinhardt, R.,
Greulich, S.,
Wanner, M.,
Fiedler, J.,
Duboc-Toia, C.,
...
What a difference ancillary thienyl makes: Unexpected additional stabilization of the diruthenium(III,II) but not the diosmium(III,II) mixed-valent state in tetrazine ligand-bridged complexes (2003)
Sarkar, B.,
Kaim, W.,
Klein, A.,
Schwederski, B.,
Fiedler, J.,
Duboc-Toia, C.,
...
Proof of innocence for the quintessential noninnocent ligand TCNQ in its tetranuclear complex with four [fac-Re(CO)3(bpy)]+ groups: Unusually different reactivity of the TCNX ligands (TCNX = TCNE, TCNQ, TCNB) (2003)
Hartmann, H.,
Kaim, W.,
Wanner, M.,
Klein, A.,
Frantz, S.,
Duboc-Toia, C.,
...
Multifrequency EPR study and density functional g-tensor calculations of persistent organorhenium radical complexes (2002)
Frantz, S.,
Hartmann, H.,
Doslik, N.,
Wanner, M.,
Kaim, W.,
...
The dinuclear radical anion complexes {(mu- L)[Re(CO)(3)Cl](2)}(.-), L = 2,2'-azobispyridine (abpy) and 2,2'-azobis(5-chloropyrimidine) (abcp), were investigated by EPR at 9.5, 94, 230, and 285 GHz...
An electrochemical, spectroelectrochemical, and computational (DFT) study of oxidation of [M(CO)4(N,N)]; M = Cr, W; N,N = 1,10-phenathroline or 3,4,7,8-tetramethyl-1,10-phenanthroline. (2001)
Farrel, I.R.,
Hartl, F.,
Zalis, S.,
Werner, M.,
Kaim, W.,
Vlcek, A. Jr.
The closo-Cluster Triad: B9X9, [B9X9].-, and [B9X9]2- with Tricapped Trigonal Prisms (X = Cl, Br, I). Syntheses, Crystal and Electronic Structures (1999)
Binder,H.,
Kellner,R.,
Vaas,K.,
Hein,M.,
Baumann,F.,
Wanner,M.,
...
HB9X9 and H2B9X9 (X = Cl, Br, I): Neutral closo-Nonaboranes in the Novel Series BnHn+1, and BnHn+2 - Syntheses, Ab Initio Calculations, and Electronic Structures (1999)
Binder,H.,
Kellner,R.,
Vaas,K.,
Hein,M.,
Baumann,F.,
Wanner,M.,
...
High-frequency (245 GHz) and X-band EPR study of stable dicopper radical complexes. (1999)
Barra, A. L.,
Brunel, L. C.,
Baumann, F.,
Schwach, M.,
Moscherosch, M.,
Kaim, W.
The closo-cluster triad: B9X9, [B9X9]2- with tricapped trigonal prisms (X = Cl, Br, I). Syntheses, crystals and electronic structures. (1999)
Binder, H.,
Kellner, R.,
Vaas, K.,
Hein, M.,
Baumann, F.,
Wanner, M.,
...
HB9X9- and H2B9X9 (X = Cl, Br, I): Neutral closo-nonaboranes in the novel series BnHn+1, and BnHn+2 - Syntheses, ab initio calculations, and electronic structures. (1999)
Binder, H.,
Kellner, R.,
Vaas, K.,
Hein, M.,
Baumann, F.,
Wanner, M.,
...
The closo-Cluster Triad: B9X9, [B9X9].-, and [B9X9]2- with Tricapped Trigonal Prisms (X = Cl, Br, I). Syntheses, Crystal and Electronic Structures (1999)
Binder, H.,
Kellner, R.,
Vaas, K.,
Hein, M.,
Baumann, F.,
Wanner, M.,
...
HB9X9 and H2B9X9 (X = Cl, Br, I): Neutral closo-Nonaboranes in the Novel Series BnHn+1, and BnHn+2 - Syntheses, Ab Initio Calculations, and Electronic Structures (1999)
Binder, H.,
Kellner, R.,
Vaas, K.,
Hein, M.,
Baumann, F.,
Wanner, M.,
...
Theoretical and experimental study of diamagnetic and paramagnetic products from thermal and light-induced alkyl transfer between zinc or magnesium dialkyls and 1,4-diaza-1,3-butadiene substrates (1991)
Koten, G. Van,
Kaupp, M.,
Stoll, H.,
Preuss, H.,
Kaim, W.,
Stahl, T.,
...